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    • 专利摘要:
    SURFACTING COMPOSITIONS AND FORMULATIONS WITH HIGH OIL CONTENT UNDERSTANDING SUCH COMPOSITIONS. The invention relates to compositions that can be used to prepare structured formulations, to structured formulations comprising such compositions and to processes for preparing structured formulations.
    公开号:BR102015008828B1
    申请号:R102015008828-0
    申请日:2015-04-17
    公开日:2020-11-10
    发明作者:Jochen Kleinen；Uta Kortemeier；Christian Hartung；Joachim Venzmer
    申请人:Evonik Operations Gmbh；
    IPC主号:
    专利说明:

    FIELD OF THE INVENTION
    [01] The invention relates to compositions that can be used for preparing structured formulations, with structured formulations comprising such compositions and with processes for preparing structured formulations. BACKGROUND OF THE INVENTION
    [02] Structured formulations containing surfactants are liquid crystalline compositions in which surfactants are present in the form of flat and / or spherolytic lamellar phases. Usually, the surfactant phases are present in the dispersed form as spherolites, that is, as lamellar droplets in the aqueous phase. These spherolites consist of an onion-like configuration with double concentric layers of surfactant molecules between which water or electrolyte solution is trapped. Structured surfactant compositions are typically pumpable non-Newton compositions capable of promoting suspension of water-insoluble particles, such as, e.g., oil droplets, by virtue of the presence of these lamellar surfactant phases.
    [03] These structured formulations are used, for example, in cosmetic hygiene formulations such as shampoos, shower gels, soaps, facial cleansers, foam formulations for bath and body care such as lotions, creams, conditioners, products for shaving and baby care formulations.
    [04] An excellent property of these structured formulations is their ability to efficiently deposit substances present on a surface by adding water.
    [05] WO 2008118381 describes structured surface-action compositions comprising, based on 100 parts by weight of the composition: I)) more than 0 to about 15 parts by weight of an alkyl ether sulfate surfactant; J) I) more than 0 to about 15 parts by weight of an alkyl sulfate surfactant; K) II) more than 0 to about 8 parts by weight of an alkanolamide-based surfactant; L) V) 0 to about 10 parts by weight of an amphoteric surfactant; with the proviso that the total quantity of components (I), (II), (UI) and (IV) is greater than or equal to 5 parts by weight; V)) an amount of an electrolyte that, in combination with components (I), (II), (III) and (IV), promotes the production of a structured surfactant composition with an opaque visual appearance and a higher yield point at 0 pascal; and W) I) water.
    [06] A disadvantage of the formulations described in the prior art is that they do not have a particularly satisfactory foaming behavior.
    [07] The necessary content of alkyl ether sulfates in prior art formulations is also disadvantageous.
    [08] Another disadvantage of structured formulations of the prior art is that the proportion between surfactants and contained oils is high.
    [09] It was a purpose of the invention to provide structured foaming formulations quickly with high oil fraction, such as, for example, 20-60% by weight, based on the total formulation. DESCRIPTION OF THE INVENTION
    [010] Surprisingly, it has been found that, with the aid of the composition according to Claim 1, it is possible to prepare quickly foaming structured formulations with high oil fraction. Since dialkyl-sulfosuccinates, as described, for example, in US3650964, they are generally known as surfactants with inadequate foaming and, in particular, also formulations with high oil content, which comprise, for example, more than 10% by weight oil, normally exhibit only low foaming in cosmetic applications, the present invention is very surprising.
    [011] The present invention, therefore, provides compositions as described in Claim 1.
    [012] The present invention further provides structured formulations comprising the compositions according to the invention.
    [013] The present invention, furthermore, further provides processes for preparing the formulations structured according to the invention.
    [014] An advantage of the present invention is that large amounts of oil can be incorporated into the formulations according to the invention.
    [015] Another advantage of the present invention is that the formulations according to the invention can be prepared without sulfate, in particular without ether-sulphate.
    [016] An additional advantage of the present invention is that the formulations according to the invention can be prepared without polyether.
    [017] Yet another advantage of the present invention is that the formulations according to the invention can stably comprise a very large amount of oil, based on the amount of surfactant present.
    [018] It is an additional advantage that the formulations can be formulated with very mild properties with regard to the skin and the potential for eye irritation.
    [019] Another advantage of the present invention is that the formulations according to the invention are stable during storage, both at high and low temperatures, as well as in temperature fluctuations.
    [020] Another advantage of the present invention is that the formulations according to the invention can stably comprise fragrances, active ingredients and care substances and have the ability to deposit them in a high degree. This provides the advantage that, e.g., the fragrance is spread evenly over the surface and is released over an extended period. Another advantage of the present invention is that the formulations according to the invention can be partially prepared at low temperatures and / or without consuming a large amount of energy.
    [021] In addition, another advantage of the present invention is that the formulations according to the invention can be formulated without fatty acids and fatty alcohols. An additional advantage of the present invention is that the formulations according to the invention can have a yield point without the addition of polymeric rheological additives.
    [022] Another advantage of the present invention is that the formulations according to the invention are highly foaming despite the high oil fraction.
    [023] Another advantage of the present invention is that the formulations according to the invention can be easily rinsed.
    [024] In addition, another advantage of the present invention is that the sensation on the skin is improved during or after washing.
    [025] An additional advantage of the present invention is the improved wash resistance of oxidative hair dyes.
    [026] Another advantage of the present invention is that the formulations according to the invention promote, through application to the hair, improved shine and improved conditioning of the hair.
    [027] In addition, another advantage of the present invention is the special creaminess and rich texture of the formulations obtainable. Furthermore, this texture can be maintained without adding relatively large amounts of salt.
    [028] The composition according to the invention comprises: X) 20 parts by weight at 67 parts by weight, preferably 25 parts by weight at 57 parts by weight, in particular preferably 33 parts by weight at 47 parts θm weight, of at least one substance selected from dialkyl-sulfosuccinates and dialkyl-methylsulfosuccinates; Y) 15 parts by weight to 40 parts by weight, preferably 20 parts by weight to 32 parts by weight, in particular preferably 23 parts by weight to 28 parts by weight, of at least one amphoteric surfactant; and Z) 15 parts by weight to 40 parts by weight, preferably 20 parts by weight to 32 parts by weight, in particular preferably 23 parts by weight to 28 parts by weight, of at least one anionic surfactant.
    [029] Within the scope of the present invention, it is understood that the term "surfactant" has the meaning of organic substances with active interface properties that have the ability to reduce the surface tension of water at 20 ° C and a concentration of 0 , 5% by weight, based on the total composition, to less than 45 mN / m. The surface tension is determined here by the ring method according to DuNoüy at 25 ° C.
    [030] Within the scope of the present invention, the term "alkyl" includes alkyl radicals that can optionally be unsaturated.
    [031] Within the scope of the present invention, it is understood that the term "amphoteric surfactant" means a zwitterionic surfactant in which, at a pH of 7 and at 20 ° C, at least 90 mol% of the molecules in each case have at least a negatively and positively charged group. It is preferable that they have an isoelectric point of pHIEP = 2-12 at 25 ° C, the determination being made in a 10 millimolar aqueous solution of potassium chloride as standard electrolyte.
    [032] Within the scope of the present invention, it is understood that the terminology "anionic surfactant" means a surfactant in which, at pH 7 and at 20 ° C, at least 90 mol% of the molecules have at least one negatively charged group. It is preferable that they do not have an isoelectric point of pHIEP = 2-12 at 25 ° C, the determination being made in a 10 millimolar aqueous solution of potassium chloride as standard electrolyte. Dialkylmethylsulfosuccinates are excluded here.
    [033] Unless otherwise stated, all percentages (%) established are percentages by mass. If, in preferred embodiments of the present invention, one or more of the components contained are limited to at least one defined substance, then it should be understood that no other substance in the component except that specified is present in the composition or formulation.
    [034] Preferably, dialkylsulfosuccinates and / or dialkylmethylsulfosuccinates present in the composition according to the invention are selected from the group consisting of dialkylsulfosuccinates and / or dialkylmethylsulfosuccinates, where the alkyl radicals are preferably 4 to 24 6 to 18, in particular preferably 6 to 14, carbon atoms. Alkyl radicals can be straight or branched, with the branched chain being preferred. Different or identical alkyl radicals can be present in a dialkyl sulfosuccinate and / or dialkyl methyl sulfosuccinate molecule, with identical ones being preferred.
    [035] As a contrion of the sulfonic acid group, preferably alkali metal cations, alkaline earth metal cations or ammonium ions, in particular sodium, can be used.
    [036] Dialkyl-Sulfosuccinates in particular preferably present are selected from the group consisting of Sodium Diethyl-Hexyl-Sulfosuccinate, Sodium Dinonyl-Sulfosuccinate, Sodium Di-Isononyl-Sulfosuccinate, Sodium Dioctyl-Sulfosuccinate, Di-Heptil-Sulfosuccinate Sodium, Sodium Di-Hexyl-Sulfosuccinate, Sodium Dineopentyl-Sulfosuccinate, Sodium Di-Isoamyl-Sulfosuccinate, Sodium Dipentyl-Sulfosuccinate, Sodium Diamyl-Sulfosuccinate, Sodium Dibutyl-Sulfosuccinate, Di-Sulfosuccinate , Dicapril-Sodium Sulfosuccinate, Sodium Didecyl-Sulfosuccinate, Sodium Diundecyl-Sulfosuccinate, Sodium Dilauryl-Sulfosuccinate, Sodium Dicocoyl-Sulfosuccinate, Sodium Ditridecyl-Sulfosuccinate-Diicylic-Hepyl-Sulphate Sodium, Ammonium Diethyl-Hexyl-Sulfosuccinate, Ammonium Dinonyl-Sulfosuccinate, Ammonium Di-Isononyl-Sulfosuccinate, Ammonium Dioctyl-Sulfosuccinate, Am-Di-Heptyl-Sulfosuccinate onium, Ammonium Di-Hexyl-Sulfosuccinate, Ammonium Dineopentyl-Sulfosuccinate, Ammonium Di-Isoamyl-Sulfosuccinate, Ammonium Dipentyl-Sulfosuccinate, Ammonium Diamyl-Sulfosuccinate, Ammonium Dibutyl-Sulfosuccinate, Di-Amylosulfonate Dicapril- Ammonium Sulfosuccinate, Ammonium Didecyl-Sulfosuccinate, Ammonium Diundecyl-Sulfosuccinate, Ammonium Dilauryl-Sulfosuccinate, Ammonium Dicocoyl-Sulfosuccinate, Ammonium Ditridecyl-Sulfosuccinate-Dipropyl-Heptil-Sulfosuccinate Ammonium, Potassium Diethyl- Hexyl-Sulfosuccinate, Potassium Dinonyl-Sulfosuccinate, Potassium Di-Isononyl-Sulfosuccinate, Potassium Dioctyl-Sulfosuccinate, Potassium Di-Heptyl-Sulfosuccinate, Potassium Di-Hexyl-Sulfosuccinate, Potassium Di-Hexyl-Sulfosuccinate Potassium, Potassium Di-Isoamyl-Sulfosuccinate, Potassium Dipentyl-Sulfosuccinate, Potassium Diamyl-Sulfosuccinate, Potassium Dibutyl-Sulfosuccinate, Di-Isobutyl-Sulfosuccin Potassium act, Potassium Dicapril-Sulfosuccinate, Potassium Didecyl-Sulfosuccinate, Potassium Diundecyl-Sulfosuccinate, Potassium Dilauryl-Sulfosuccinate, Potassium Dicocoyl-Sulfosuccinate, Potassium Dioxide-Sulfosuccinate, Potassium Dioxide Potassium Hexyl-Sulfosuccinate, Sodium Diethyl-Hexyl-MethylSulfosuccinate, Sodium Dinonyl-MethylSulfosuccinate, Sodium Di-Isononyl-Methylsulfosuccinate, Sodium Dioctyl-MethylSulfosuccinate, Di-Heptyl-MethylSulfosuccinate Sodium Dineopentyl-MethylSulfosuccinate, Sodium Di-Isoamyl-Sulfosuccinate, Sodium Dipentyl-MethylSulfosuccinate, Sodium Diamyl-MethylSulfosuccinate, Sodium Dibutyl-MethylSulfosuccinate, Di-Isobutyl-Sulfyl-Sulfyl-Sulfate, Tip Sodium, Diundecyl-MethylSulfosuccinate, Sodium Dilauryl-MethylSulfosuccinate, Sodium Dicocoyl-MethylSulfosuccinate Sodium, Sodium Ditridecyl-MethylSulfosuccinate, Sodium Dipropyl-Heptyl-MethylSulfosuccinate, Sodium Dicyclohexyl-MethylSulfosuccinate, with Diethyl-Hexyl-Sodium Sulfosuccinate being particularly particularly preferred.
    [037] Preferably, amphoteric surfactants present in the composition according to the invention are selected from the group comprising, preferably consisting of, alkylbetaines, alkylamidoalkylbetaines, alkylamphoacetates, alkylamphodiacetates, alkylamphopropionates, alkylamphodipropionates, alkylsultainates, alkylsulfates -hydroxysultainas, alkylamine oxides, alkyl-amphoglycinates, alkyl-iminodiacetates, alkyl-iminodipropionates, alkyl-amphopropylsulfonates, alkyl-amphocarboxyglycinates and alkyl-amphocarboxypropionates.
    [038] In particular preferably, amphoteric surfactants present in the composition according to the invention are selected from the group comprising, preferably consisting of, C4- to C24- alkylbetaines, preferably C6- to C18-, in particular preferably C8- to C14 -, and C4- to C24- alkylamidopropyl betaines, preferably C6- to C18-, in particular preferably C8- to C14-. Alkyl radicals can be straight or branched, with the straight chain being preferred. Alkylbetaines or alkylamidopropylbetains in particular preferably present are selected from the group consisting of Lauryl-Betaine, Coco-Betaine, Behenyl-Betaine, Capril / Capramidopropyl-Betaine, Cetyl-Betaine, Cocamidoethyl-Betaine, Cocamidopropyl-Betaine, Coco / Oleamidopropyl-Betaine Decyl-Betaine, Dimer-Dilinoleamidopropyl-Betaine, Hydrogenated Tallow Betaine, Hydroxylauryl / Hydroxy-systyl-Betaine, Isoestearamidopropyl-Betaine, Lauramidopropyl-Betaine, Lauryl-Betaine, Myristyl-Betaine, Oleamidopropyl-Betaine, Oleyl-Betaine-Olein, Palmit -Betaine, Stearamidopropyl-Betaine, Stearyl-Betaine, Sebum Starch, Betaine, Sebum Dihydroxyethyl-Betaine, Undecylenamidopropyl-Betaine, Sunflower Amidopropyl-Betaine, Cetyl-Betaine, Lauryl-Betaine.
    [039] Particularly preferably, alkyl anphonacetates, alkyl amphodiacetates, alkyl amphopropionates or alkyl amphodipropionates present according to the invention as amphoteric surfactants are selected from the group consisting of Cocobetainamido-Anfopropionato, DEA-Cocoanfodipropionato, Caproanfodiacato, Caproanfodiacato Disodium, Capriloanfodipropionato disodium, disodium cocoamphodiacetate, disodium Cocoanfodipropionato, Disodium Isoestearoanfodiacetato, Isoestearoanfodipropionato Disodium lauryl ether Disodium 5-Carboxianfodiacetato, Lauroanfodiacetato disodium, Disodium Lauroanfodipropionato, Oleoanfodipropionato Disodium PPG-2-Isodeceto-7- Carboxianfodiacetato Disodium, Disodium Estearoanfodiacetato, the Anfodiacetato Sodium Sebum, Sodium Caproanphopropionate, Sodium Capriloanfoacetate, Sodium Capriloanphopropionate, Sodium Cocoanfoacetate, Sodium Cocoanphopropionate, Sodium Isoestearoanfoacetate, Sodium Isoestearoanopropropionate, Lauroanaphate to Sodium, Sodium Lauroanphopropionate, Sodium Miristoanfoacetate, Sodium Oleoanfoacetate, Sodium Oleoanphopropionate, Sodium Estearoanfoacetate, Sodium Stearoanphopropionate, Sodium Sebum Anhydride, Sodium Anhydrous Sodium Anhydrous Sodium, Anhydrous Sodium Sodium Anhydrous Sodium.
    [040] Particularly preferably, alkylstaines or alkylhydroxysulfates present according to the invention as amphoteric surfactants are selected from the group consisting of Capril-Sultaina, Cocamidopropyl-Hydroxisultaine, Coco-Hydroxysultaine, Coco-Sultaina, Erucamidopropil-Hydroxisultaina, Lauram Hydroxysultaine, Lauryl-Hydroxysultaine, Lauryl-Hydroxysultaine, Miristamidopropyl-Hydroxysultaine, Oleamidopropyl-Hydroxysultaine, Amidopropyl-Hydroxysultin of Sebum
    [041] In particular preferably, alkylamine oxides present as amphoteric surfactants are selected from the group consisting of Behenamine Oxide, Cocamine Oxide, Decylamine Oxide, Deciltetradecylamine Oxide, Dihydroxyethyl C8-10-Aloxypropylamine Oxide Dihydroxyethyl C9-11- Aloxypropylamine, Dihydroxyethyl oxide C12-15- Aloxypropylamine, Dihydroxyethyl-cocamine oxide, Dihydroxyethyl laurine oxide, Dihydroxyethyl stearamine oxide, Dihydroxyethyl oxide Sebum Amine, Hydrogenated Sebum Amine Oxide, Iso-Stearamidopropylamine Oxide, Lauramidopropylamine Oxide, Lauramine Oxide, Miristamidopropylamine Oxide, Myristamine Oxide, Palmitamine Propylamine Oxide, Lauramidopropylamine Oxide, Lauryl Oxide, PEGyl Oxide-3-Oxide-Oxide-Pylamine-Oxide, PEG-3-Oxide. , Stearamine Oxide, Tallow Amidopropylamine Oxide, Tallow Amine Oxide, Undecylenamidopropylamine Oxide.
    [042] Particularly preferably, alkyl amphoglycinates present as amphoteric surfactants are selected from the group consisting of Caproanfoglicinato, Capriloanfoglicinato, Cocoanfoglicinato, Isoestearoanfoglicinato, Lauroanfoglicinato, Miristoanfoglicinato, Oleoanlicogatoato, Anticooglicinato, Anticooglicinato, Anticooglicinato, Anticooglicinato, Anticoagulato.
    [043] Particularly preferably, alkyl iminodiacetates or alkyl iminodipropionates present as amphoteric surfactants are selected from the group consisting of Disodium Cocaminopropyl-Iminodiacetate, Disodium Hydroxyethyliminodiacetate, Disodium Lauriminodiacethate, Disodium Lauroiminodipropionate, Disseminated C12-15 Sodium, Sodium Cocoiminodiacetate, Sodium Lauriminodipropionate.
    [044] Particularly preferably, alkyl amphopropylsulfonates present as amphoteric surfactants are selected from the group consisting of Sodium Cocoanfo-hydroxypropylsulfonate, Sodium Lauroanfo-hydroxypropylsulfonate, Sodium Oleoanfo-hydroxypropylsulfonate, Stearoanfo-hydroxypropylsulfonate, Sodium bisulfonate Disodium, Sodium Cocoanfocarboxyethyl-hydroxypropylsulfonate, Sodium Caproanfo-hydroxypropylsulfonate, Sodium Capriloanfo-hydroxypropylsulfonate.
    [045] Most particularly preferably, the amphoteric surfactant present is Cocamidopropyl-Betaine.
    [046] Preferably, anionic surfactants present in the composition according to the invention are selected from the group comprising, preferably consisting of, alkyl sulfates, alkyl ether sulfates, optionally alkoxylated sulfosuccinates, optionally alkoxylated methylsulfosuccinates, optionally alkoxylated sulfonates, optionally alkoxylated glycinates, optionally alkoxylated glutamates, optionally alkoxylated isethionates, optionally alkoxylated carboxylates, optionally alkoxylated anisates, optionally alkoxylated levulinates, optionally alkoxylated tartrates, optionally alkoxylated lactylates, optionally alkoxylated sulfates, optionally alkoxylated sulfates, optionally alkoxylates , optionally alkoxylated sarcosinates and optionally alkoxylated phosphonates. In this context, dialkyl-sulfosuccinates are excluded from sulfosuccinates and dialkyl-methylsulfosuccinates are excluded from methylsulfosuccinates.
    [047] Preferably, alkyl sulfates or alkyl ether sulfates present as anionic surfactants in the composition according to the invention are selected from the group consisting of alkyl sulfates and alkyl ether sulfates C4- to C24-, preferably C6- to C18-, in particular preferably C8- to C14-. Alkyl radicals can be straight or branched, with the straight chain being preferred. Suitable branched-chain alkyl radicals include methylldecyl groups, methylundecyl groups, methylldecyl groups, ethylldecyl groups and ethildodecyl groups, such as, for example, 1-methylldecyl, 1-methylundecyl, 1-methylldecyl, 1-ethylldecyl, 1-ethylundecyl and 1-ethyldodecyl.
    [048] The addition of an alkyl or alkenyl group with the suffix "eto" generally describes the addition of one or more ethylene oxide units, that is, tridecide refers to an ethoxylated tridecyl group, and with the suffix " -n ", where n is an integer, the number of these ethylene oxide units per group, that is," Tridecet-3 "refers to an ethoxylated tridecyl alcohol group with 3 ethylene oxide units per tridecyl group .
    [049] In a preferred embodiment, the alkyl sulfate or the alkyl ether sulfate is selected from C12-15 Ammonium Alkyl Sulfate, C12-16 Ammonium Alkyl Sulfate, Ammonium Caprylide-Sulfate, Cocomonoglyceride-Sulfate Ammonium, Ammonium Coco-Sulfate, C12-15 Ammonium Pareto-Sulfate, Ammonium Lauryl Ether-Sulfate, Ammonium Lauryl Ether-5-Sulfate, Ammonium Lauryl Ether-7-Sulfate, Ammonium Lauryl Ether-9-Sulfate , Ammonium Lauryl Ether-12-Sulfate, Ammonium Lauryl-Sulfate, Ammonium Mireto-Sulfate, Ammonium Miristyl-Sulfate, Ammonium Nonoxynol-4-Sulfate, Ammonium Nonoxynol-30-Sulfate, Ammonium Sulfate, Ammonium Tridecide-Sulfate, DEA-C12-13 Alkyl-Sulfate, DEA-C12-15 Alkyl-Sulfate, DEA-Cetyl-Sulfate, DEA-C12-13 Pareto-3-Sulfate, DEA-Lauryl ether-Sulfate , DEA-Lauryl- Sulfate, DEA-Mireto-Sulfate, DEA-Miristyl-Sulfate, DEA- Tridecide-Sulfate, Diethylamine Lauryl Ether-Sulfate, Magnesium Etheto-Sulfate, Magnesium Coco-Sulfate, Magnesium Lauryl Ether-Sulfate , Laur il Magnesium Ether-5-Sulfate, Magnesium Lauryl Ether-8-Sulfate, Magnesium Lauryl Ether-16-Sulfate, Magnesium Lauryl Sulfate, Magnesium Mireto-Sulfate, Magnesium Oleto-Sulfate, PEG-3-Cocamide -Magnesium sulphate, magnesium coco-sulphate / TEA, Lauryl ether- MEA sulphate, MEA lauryl sulphate, MEA tridecide-sulphate, MIPA pareto-sulphate C12-15, MIPA lauryl ether, Lauryl- MIPA Sulfate, MIPA Tridecide-Sulfate, Mixed Isopropanolamines Lauryl-Sulfate, Potassium Lauryl Ether-Sulfate, Potassium Lauryl-Sulfate, C8-10 Sodium Alkyl-Sulfate, C10-16 Alkyl-Sulfate, Alkyl-Sulfate Sodium Cll-15, Sodium Alkyl Sulfate C12-13, Sodium Alkyl Sulfate C12-15, Sodium Alkyl Sulfate C12-18, Sodium Alkyl Sulfate C16-20, Sodium Caprylyl Sulfate, Cetearyl- Sodium Sulfate, Sodium Cetyl-Sulfate, Sodium Cholesteryl-Sulfate, Sodium Coceto-Sulfate, Sodium Coceto-30-Sulfate, Coconut Sulfate / Hydrogenated Sodium Sebum, Cocomonoglyceride-Sulfate Sodium, Sodium Coco-Sulfate, Sodium Pareto-3-Sulfate C9-15, Sodium Pareto-Sulfate C10-15, Sodium Pareto-2-Sulfate C10-16, Sodium Pareto-Sulfate C12-13, Pareto- 3-Sodium Sulfate C12-14, Sodium Pareto-Sulfate C12-15, Pareto-3-Sulfate Sodium C12-15, Pareto-3-Sodium Sulfate C13-15, Sec-Pareto-3-Sodium Sulfate C12 -14, Sodium Deceto-Sulfate, Sodium Decyl-Sulfate, Sodium Ethyl-Exyl-Sulfate, Sodium Laneto-Sulfate, Sodium Lauryl Ether-Sulfate, Sodium Lauryl Ether-5-Sulfate, Lauril Ether-7- Sodium Sulfate, Sodium Lauryl-8-Sulfate, Sodium Lauryl-12-Sulfate, Sodium Lauryl-4O-Sulfate, Sodium Lauryl-Sulfate, Sodium Cocamide-Sulfate / MEA-PEG-3, Mireto -Sodium Sulfate, Sodium Myristyl-Sulfate, Nonoxynol-1-Sodium Sulphate, Nonoxynol-3-Sodium Sulphate, Nonoxynol-4-Sodium Sulphate, Nonoxynol-6-Sodium Sulphate, Nonoxynol-8-Sodium Sulphate , Nonoxynol-10-Sodium Sulfate, Nonoxynol-25-Sodium Sulfate, Octoxynol-2-Sodium Sulfate, Octoxynol-6-S Sodium Ulfate, Sodium Octoxynol-9-Sulfate, Sodium Oleto-Sulfate, Sodium Oleyl-Sulfate, Sodium PEG-4-Cocamide-Sulfate, Sodium PEG-4-Lauramide-Sulfate, Sodium Stearyl-Sulfate, Sodium Sebum Sulfate, Sodium Pareto-3-Sulfate / TEA C12-13, Sodium Tridecide-Sulfate, Sodium Tridecyl-Sulfate, Sulfated Ricin Oil, Sulfated Coconut Oil, Sulfated Glyceryl-Oleate, Sulfated Olive Oil, Sulfated Peanut Oil, TEA-C10-15 Alkyl Sulfate, TEA-C11-15 Alkyl Sulfate, TEA-C12-13 Alkyl Sulfate, TEA-C12-14 Alkyl Sulfate, TEA Alkyl Sulfate -C12-15, TEA Coco Sulfate, TEA Pareto-Sulfate-Cll-15, TEA-C12-13 Pareto-3-Sulfate, TEA Laneto-5-Sulfate, TEA Lauryl Ether-Sulfate, Lauryl- TEA Sulfate, TEA Oleyl Sulfate, TEA-PEG-3 Cocamide-Sulfate, TEA Tridecide-Sulfate, TIPA Lauryl Ether Sulfate, TIPA Lauryl Sulfate, with Sodium Lauryl Sulfate being particularly preferred.
    [050] Preferably, optional alkoxylated sulfosuccinates and / or methyl sulfosuccinates present as anionic surfactants in the composition according to the invention are selected from the group consisting of optionally Sulfosuccinates and / or methylSulfosuccinates C4- to C24-, preferably C6- to C18-, in particularly preferably C8- to C14-alkoxylated. Alkyl radicals can be straight or branched, along the preferred straight chain. Alkoxylated sulfosuccinates and / or methylsulfosuccinates can in particular have a degree of alkoxylation between 1 and 10, in particular preferably between 2 and 5.
    [051] The alkoxy group is preferably selected from ethoxy.
    [052] Particularly preferably, optional alkoxylated sulfosuccinates are selected from the group consisting of Sodium Lauryl ether-Sulfosuccinate C12-14, Pareto-1-Sulfosuccinate Disodium C12-14, Pareto-2-Sulfosuccinate Disodium C12-14, Sec-Pareto-12-Sulfosuccinate Disodium C12-14, Sec-Pareto-3-Sulfosuccinate Disodium C12-14, Sec-Pareto-5-Sulfosuccinate Disodium C12-14, Sec-Pareto-7-Sulfosuccinate Disodium C12-14, Sec-Pareto-9- Sulfosuccinate Disodium C12 -14, Disodium Pareto-Sulfosuccinate C12-14, Di-Triethanolamine Oleamido-PEG-2-Sulfosuccinate, Disodium Oleamido-PEG-2-Sulfosuccinate, Disodium Cocamido-Monoisopropanolamine-PEG-4-Sulfosuccinate Sulphate-PEG-4-Sulfosuccinate 4 Disodium, Coceto-3-Sulfosuccinato Disodium, Cocoyl-Butyl-Glycol-10-Sulfosuccinate Disodium, Doceto-5-Sulfosuccinate Disodium, Doceto-6-Sulfosuccinate Disodium, Lauryl ether-5-Sulfosuccinate Disodium, Lauramido-PEG 2 , Lauramido-PEG-5-Sulfosuccinate Disodium, Laur il Disodium ether-Sulfosuccinate, Disodium Lauryl ether-12-Sulfosuccinate, Disodium Lauryl ether-6-Sulfosuccinate, Disodium Lauryl ether-9-Sulfosuccinate, Disodium Oleamido-PEG-2-Sulfosuccinate, Disodium-3-Sulfosuccinamide Disodium 2-Sulfosuccinate, Disodium PEG-5-Laurylcitrate-Sulfosuccinate, Palm PEG-8-Glycerides Disodium Sulfosuccinate, Disodium Sitosteride-14-Sulfosuccinate, Disodium Undecylenamide-PEG-2-Sulfosuccinate 3- Lauryl Monoethanolamine Lauryl ether-2-Sulfosuccinate, C12-14 Diammonium Pareto-l-Sulfosuccinate, C12-14 Pareto-2-Sulfosuccinate, C12-14 Sec-Pareto-12-Sulfosuccinate, Sec-Pareto-3 Sulfosuccinate C12-14 Diammonium Sulfosuccinate, C12-14 Sec-Pareto-7 Diammonium Sulfosuccinate, C12-14 Sec-Pareto-9 Pareto-9 Sulfosuccinate, C12-14 Diammonium Sulfosuccinate , 01eamido-PEG-2-Di-Triethanolamine sulfosuccinate, 01eamido-PEG-2- Diammonium Sulfosuccinate, Diammonium Cocamido-Monoisopropanolamine-PEG-4-Sulfosuccinate, Diammonium Cocamido-PEG-4-Sulfosuccinate, Diammonium Coceto-3-Sulfosuccinate, Diammonium Cocoyl-Butyl-Glycol-Sulfosuccinate-5-Decide-5 Diammonium, Diammonium Deceto-6-Sulfosuccinate, Diammonium Laneto-5- Sulfosuccinate, Diammonium Lauramido-PEG-2-Sulfosuccinate, Diammonium Lauramido-PEG-5-Sulfosuccinate, Diammonium Lauryl Ether-Sulfosuccinate, Lauryl Ether-12- Diammonium Sulfosuccinate, Diammonium Lauryl Ether-6-Sulfosuccinate, Diammonium Lauryl Ether-9-Sulfosuccinate, 01amido-PEG-2-Diammonium Sulfosuccinate, Oleto-3- Diammonium Sulfosuccinate, Palmitamido-PEG-2-Diammonium Sulfosuccinate, PEG-5-Laurylcitrate-Diammonium Sulfosuccinate, PEG-8-Glyceride Disodium Sulfosuccinate, Diammonium Sitosteride-14-Sulfosuccinate, Undecylenamide-Diammonium Lauryl-Sulfosuccinate, Diammonium Lauryl-Sulfosuccinate, Lauridamide , Lauril-Sul Diammonium phosuccinate, Dipotassium Lauryl-Sulfosuccinate, Babaçuamido- MEA-Sulfosuccinate Disodium, Cetearyl-Sulfosuccinate Disodium, Cetyl-Sulfosuccinate Disodium, Cocamido-MEA- Sulfosuccinate Sulfosodium, Cocamido-MIPA-MIPA Cottonseed Glycerides, Disodium Isodecyl-Sulfosuccinate, Disodium Isostearamido-MEA-Sulfosuccinate, Disodium Isostearamido-MIPA-Disodium Sulfosuccinate, Isostearyl-Sulfosuccinate-Sulfosuccinate, Lauramido-Sulfosuccinate, Lauramido-Sulfosuccinate , Miristamido-MEA-Sulfosuccinato Disódico, Oleamido-MEA-Sulfosuccinato Disódico, Oleamido- MIPA-Sulfosuccinato Disódico, Oleyl-Sulfosuccinato Disódico, Polyglyceril-3-Caprato / Caprilato-Sulfosuccinato Sulfido-MEodico-Ricinoleamide Disodium, Stearyl-Sulfosuccinate Disodium, Tallamido-MEA-Sulfosucci Disodium nato, Sebum-MEA-Disodium Sulfosuccinate Starch, Disodium Tridecyl-Sulfosuccinate, Disodium Undecylenamido-MEA-Sulfosuccinate, with Disodium Lauryl ether-Sulfosuccinate being particularly particularly preferred.
    [053] Preferably, optional alkoxylated sulfonates present as anionic surfactants in the composition according to the invention are selected from the group consisting of C14-16 Sodium Olefin-Sulfonate, C12-15 Sodium Pareto-15-Sulphonate, Alkyl Sec-Sulfonate Sodium C14-17, Sodium Olefin Sulfonate C14, Ammonium Cumenesulfonate, Ammonium Dodecylbenzene Sulfonate, Calcium Dodecylbenzene Sulfonate, DEA-Dodecylbenzene Sulphonate, DEA-Methyl-Miristate-Sulphonate, Deconate Disodium, Disodium Laurimino-bis- Hydroxypropyl-Sulfonate, Disodium Lauryl-Phenyl-Ether-Disulfonate, Isopropylamine Dodecylbenzene-Sulfonate, Magnesium-10-Alkyl-Benzyl-Sulfonate-Magnesium-10-Alkyl-Sulfonate, Alkaline-Sulfonate 13, MIPA Dodecylbenzene-Sulfonate, Potassium Dodecylbenzene-Sulfonate, Potassium Lauryl-Hydroxypropyl Sulfonate, C13-17 Sodium Alkane-Sulfonate, C14-18 Sodium Alkyl-Sulphonate, Alkylbenzene-Sulphonate Only dio CIO-13, Sodium Alkyl Sec-Sulfonate C9-22, Sodium Alkyl Sec-Sulfonate C14-17, Sodium Caproylethylformyl-Benzene-Sulfonate, Sodium Caprylyl-PG-Sulfonate, Sodium Caprylyl-Sulfonate, Cocoglycosides-Hydroxypropyl - Sodium Sulfonate, Sodium Cocoglyceryl-Ether-Sulfonate, Sodium Cocomonoglyceride-Sulfonate, Sodium Olefin-Sulfonate C12-14, Sodium Olefin-Sulfonate 014-18, Sodium Olefin-Sulfonate 016-18, Pareto-PG- Sodium Sulfonate C14-15, Sodium Pareto-3-Sulfonate C12-15, Sodium Pareto-7-Sulfonate C12-15, Decylbenzene-Sulfonate, Sodium Decylglycosides-Hydroxypropyl-Sulfonate, Sodium Dodecylbenzene-Sulfonate, Hydroxyprop -Palm Kernelate-Sodium Sulfonate, Sodium Lauroyl-Hydroxypropyl- Sodium Laurylglycosides-Hydroxypropyl- Sodium Sulfonate, Sodium Methyl-Laurate-Sulfonate, Sodium Methyl-Myristate-Sulfonate, Methyl-Palmitate-Sodium-Sulphonate Sodium Stearate-Sulfonate, Palm Glyceride-Sodium Sulfonate, Phenylnonanoate - Sodium Sulfonate, Sodium Tridecylbenzene-Sulfonate, TEA C14-17-Alkyl Sec-Sulfonate, TEA-Dodecylbenzene-Sulfonate, TEA-Tridecylbenzene-Sulfonate.
    [054] Preferably, optional alkoxylated glycinates present as anionic surfactants in the composition according to the invention are selected from the group consisting of Sodium Cocoyl-Glycinate, Potassium Cocoyl-Glycinate, Sodium Lauroyl-Glycinate, Sodium Lauryl-Diethylenediaminoglycinate, TEA-Cocoyl-Glycinate.
    [055] Preferably, optional alkoxylated glutamates present as anionic surfactants in the composition according to the invention are selected from the group consisting of Sodium Cocoyl-Glutamate, Sodium Cocoyl-Glutamate, Sodium Lauroyl-Glutamate, Cocoyl-Hydrolyzed Wheat Protein Sodium Glutamate, Dipotassium Capryloyl-Glutamate, Dipotassic Undecyleneyl-Glutamate, Disodium Capriloyl-Glutamate, Disodium Cocoyl-Glutamate, Sodium Hydrogenated-Glutamate, Disodium Lauroyl-Glutamate, Disodium-Glutamate, Glutamate-Glutamate Potassium, Potassium Cocoyl-Glutamate, Potassium Lauroyl-Glutamate, Potassium Miristoil-Glutamate, Potassium Stearoyl-Glutamate, Undecyleneyl-Potassium Glutamate, Sodium Capryloyl-Glutamate, Sodium Cocoyl-Glutamate, Coconut / Hydrogenated / Coconut Sodium Glutamate, Cocoil-Hydrolyzed Wheat Protein- Sodium Glutamate, Cocoil / Palmoil / Sunfloweroyl-Sodium Glutamate, Sebum Oil the Hydrogenated-Sodium Glutamate, Sodium Lauroyl-Glutamate, Sodium Miristoil-Glutamate, Sodium Olivoyl-Glutamate, Sodium Palmoil-Glutamate, Sodium Estearoil-Glutamate, Sodium Undecyleneyl-Glutamate, TEA-Cocoil-Glutamate - Hydrogenated tallow oil - Glutamate, TEA-Lauroyl-Glutamate.
    [056] Preferably, optional alkoxylated isethionates present as anionic surfactants in the composition according to the invention are selected from the group consisting of Sodium Lauroyl-Methyl-Isetionate, Sodium Cocoyl-Isetionate, Ammonium Cocoyl-Isetionate, Cocoyl-Isetionate of Sodium, Hydrogenated Cocoyl-Methyl- Sodium Isethionate, Sodium Lauroyl-Isethionate, Sodium Lauroyl-Methyl-Isetionate, Sodium Miristoyl-Isethionate, Sodium Oleyl-Methyl-Isetionate, Palm Kernel Oil- Sodium Isethionate, Stearoyl-Methyl -Sodium ionthionate.
    [057] Preferably, optional alkoxylated carboxylates present as anionic surfactants in the composition according to the invention are selected from the group consisting of Sodium Tridecide-7-Carboxylic Acid, Lauryl ether-13-Carboxylate, Sodium Lauryl ether-4-Carboxylate , Lauryl ether-ll-Carboxylic Acid, Lauryl ether-5-Carboxylic Acid, Lauryl ether-5-Carboxylate, Sodium Lauryl ether-6-Carboxylate, Lauryl ether-8- Arnone Carboxylate, Caprylide-4-Carboxylic Acid , Caprylide-6-Carboxylic Acid, Caprylide-9-Carboxylic Acid, Cetearide-25-Carboxylic Acid, Cetyl C-12-15- Pareto-8-Carboxylate, Cetyl C12-15-Pareto-9-Carboxylate, Cetyl-PPG- 2-Isodecide-7-Carboxylate, Coceto-7-Carboxylic Acid, Pareto-6 C9-ll-Carboxylic Acid, Pareto-8 C9-11-Carboxylic Acid, Pareto-7 Cll-15-Carboxylic Acid, Pareto-5 C12- 13-Carboxylic Acid, Pareto-7 C12-13-Carboxylic Acid, Pareto-8 C12-13-Carboxylic Acid, Pareto-12 C12-13-Carboxylic Acid, Pareto-7 C12-15-Carboxic Acid ilico, Pareto-8 C12-13-Carboxylic Acid, Pareto-12 C12-15-Carboxylic Acid, Pareto-8 C14-15-Carboxylic Acid, Deceto-7-Carboxylic Acid, Ethyl-Exeto-3-Carboxylic Acid, Hexeto- 4-Carboxylic Acid, Isopropyl C12-15- Pareto-9-Carboxylate, Ispropyl-PPG-2-Isodecide-7-Carboxylate, Isoestearide-6-Carboxylic Acid, Iostearide-11-Carboxylic Acid, Lauryl ether-3-Carboxylic Acid, Lauryl ether-4-Carboxylic acid, Lauryl ether-5-Carboxylic acid, Lauryl ether-6-Carboxylic acid, Lauryl ether-8-Carboxylic acid, Lauryl ether-10-Carboxylic acid, Lauryl ether-11-Carboxylic acid, Lauryl ether - 12-Carboxylic acid, Lauryl ether-13-Carboxylic acid, Lauryl ether-14-Carboxylic acid, Lauryl ether-17-Carboxylic acid, Lauryl ether-11-Carboxylate, MEA- Lauryl ether-6-Carboxylate, MEA- PPG-6-Lauryl ether-7-Carboxylate, MEA-PPG-8-Stearide-7-Carboxylate, Mireto-3-Carboxylic Acid, Mireto-5-Carboxylic Acid, Oleto-3-Carboxylic Acid, Oleto-6-Carboxylic Acid , Oleto-10- Carbo Acid xylic, PEG-2-Stearamide-Carboxylic Acid, PEG-9-Stearamide-Carboxylic Acid, Potassium Lauryl Ether-3-Carboxylate, Potassium Lauryl Ether-4-Carboxylate, Potassium Lauryl Ether-5-Carboxylate, Lauryl Ether-Lauryl Potassium 6-Carboxylate, Potassium Lauryl Ether-10-Carboxylate, Potassium Tridecide-3-Carboxylate, Potassium Tridecide-4-Carboxylate, Tridecide-7-Potassium Tridecide-15-Carboxylate, Tridecide-19-Tridecide-19 -Potassium Carboxylate, C12- 15-Pareto-8-Carboxylate, Sodium Caprylide-2-Carboxylate, Sodium Caprylide-9-Carboxylate, Sodium Cetearide-13-Carboxylate, Sodium Keteto-13-Carboxylate, Pareto- 6 C9-11- Sodium Carboxylate, Pareto-7 Sodium Cll-15-Carboxylate, Pareto-5 C12-13-Sodium Carboxylate, Pareto-8 C12-13- Sodium Carboxylate, Pareto-12 C12-13-Carboxylate Sodium, Pareto-6 C12-15-Sodium Carboxylate, Pareto-7 C12-15-Sodium Carboxylate, Pareto-8 C12-15-Sodium Carboxylate, Pareto-12 C12-15-Sodium Carboxylate, Pareto-8 C14- 1 Sodium 5-Carboxylate, Sodium-Pareto-8 C12-14-Sodium Carboxylate, Sodium Deceto-2-Carboxylate, Sodium Hexeto-4-Carboxylate, Sodium Isostearide-6-Sodium Carboxylate, Sodium Isoestearide-ll-Carboxylate , Sodium Lauryl ether-3-Carboxylate, Sodium Lauryl ether-4-Carboxylate, Sodium Lauryl ether-5-Carboxylate, Sodium Lauryl ether-6-Carboxylate, Sodium Lauryl ether-8-Carboxylate, Lauryl ether-ll -Sodium carboxylate, Sodium Lauryl ether-12- Sodium Lauryl ether-13-Sodium carboxylate, Sodium Lauryl ether-14-Sodium Lauryl ether-16- Sodium Lauryl ether-17-Carboxylate, Sodium Lauryl-Glucose-Carboxylate, Sodium Lauryl-Glycol-Carboxylate, Sodium PEG-6-Cocamide-Carboxylate, Sodium PEG-8-Cocamide-Carboxylate, Sodium PEG-3-Lauramide-Carboxylate, PEG-4- Sodium Lauramide-Carboxylate, Sodium PEG-7-Olive Oil-Sodium Carboxylate, Sodium PEG-8-Palm Glycerides, Sodium Tridecide-6-Carboxylate, Sodium Tridecide-4-Carboxylate, Tridece to-6- Sodium Carboxylate, Sodium Tridecide-7-Sodium Carboxylate, Sodium Tridecide-8-Carboxylate, Sodium Tridecide-12-Carboxylate, Sodium Tridecide-15-Carboxylate, Sodium Tridecide-19- Carboxylate, Undecide- Sodium 5-Carboxylate, Tridecto-3-Carboxylic Acid, Tridecide-4-Carboxylic Acid, Trideceto-7-Carboxylic Acid, Tridecide-8-Carboxylic Acid, Trideceto-15-Carboxylic Acid, Trideceto-19-Carboxylic Acid 5-Carboxylic acid.
    [058] Preferably, optional alkoxylated sarcosinates present as anionic surfactants in the composition according to the invention are selected from the group consisting of Sodium Lauroyl-Sarcosinate, Sodium Cocoyl-Sarcosinate, Sodium Miristoil-Sarcosinate, TEA-Cocoil-Sarcosinate, Ammonium Cocoyl-Sarcosinate, Ammonium Lauroyl-Sarcosinate, Dimero Dilinoleil-bis- Lauroylglutamate / Lauroilsarcosinate, Lauroanfodiacetato- Lauroil-Sarcosinato Disodium, Isopropyl-Lauroyl-Sarcosinate, Potassium Cocoyl Sarcosinate, Lauroil-Sarcosinate, Lauroil Sodium, Sodium Lauroyl-Sarcosinate, Sodium Miristoil-Sarcosinate, Sodium Oleoyl-Sarcosinate, Sodium Palmitoyl-Sarcosinate, TEA-Cocoil-Sarcosinate, TEA-Lauroyl-Sarcosinate, TEA-Oleoil-Sarcosinate, TEA-Palmiste-Sarcosinato.
    [059] Other substances that may be present as anionic surfactants in the composition according to the invention are selected from the group consisting of Sodium Anisate, Sodium Levulinate, Sodium Coco-Glycoside-Tartrate, Sodium Lauroyl-Lactylate, Methyl- Sodium Cocoyl-Taurate, Sodium Methyl-Lauroyl-Taurate, Sodium Methyl-Oleoyl-Taurate, Sodium Cocoyl-Alaninate, Sodium Lauryl Ether-4-Phosphate, Lauryl Ether-l-Phosphate, Lauryl Ether-3-Phosphate , Potassium Lauryl Ether-1-Phosphate, Sodium Lauryl-Sulfoacetate and Sodium Coco-Sulfoacetate, Disodium Stearyl-Sulfossuccinnamate, Disodium Tallet Sulfosuccininamate, Dicarboxyethyl-Stearyl-Sulfossuccinate Tetra-sodium and their respective alkoxylated variants and their alcoholic variants.
    [060] It is preferred, according to the invention, if the composition according to the invention additionally comprises a component: AA) 0 part by weight to 15 parts by weight, preferably 5 parts by weight to 12 parts by weight, in particular preferably 7 parts by weight to 10 parts by weight, of at least one hydrophobic thickener.
    [061] Preferred hydrophobic thickeners that are preferably present in the formulation according to the invention are selected from the group comprising, preferably consists of: products of the reaction of at least one fatty acid and / or at least one fatty acid ester, such as, for example, fatty acid esters with glycerol, fatty acid methyl esters and fatty acid ethyl esters, with at least one primary or secondary amine, wherein the amine preferably also also comprises one or more other functional groups such as, for example, alcohols , and cationic surfactants in which, at pH 7 and 20 ° C, at least 90 mol% of the molecules have at least one positively charged group and preferably do not have an isoelectric point of pHIEP = 2-12 at 25 ° C, the determination being made in an aqueous solution of 10 millimolar potassium chloride as standard electrolyte.
    [062] Preferably, hydrophobic thickeners present in the composition according to the invention are selected from the group comprising, preferably consists of, alkylamidic monoethanolamines, alkylamidic diethanolamines, alkylamidic monoisopropanolamines, ethoxylated fatty acid amides, fatty alcohol ethoxylates, alkyl quats and alkyls alkylamidoalkyls.
    [063] Preferably, alkylamidic monoethanolamines, alkylamidic diethanolamines and alkylamidic monoisopropanolamines present as hydrophobic thickeners in the composition according to the invention are selected from the group comprising, preferably consisting of, alkylamidic monoethanolamines, alkylamidine monoamylamine and alkylamidylsamines24 C6- to C18-, in particular preferably C8- to C14-. Alkyl radicals can be straight or branched, with the straight chain being preferred. In particular preferably, alkylamide monoethanolamines, alkylamide diethanolamines and alkylamide monoisopropanolamines present are selected from the group consisting of Cocamide-Monoethanolamine (= Cocamide MEA), Mincamide-Diethanolamine, Olivoamide-Monoethanolamine, palm kernel-amide-amide-amide-amide, palm-amide-amide-amide-amide-amide-amide, palm-amide-amide-amide-amide-amide, palm-amide-amide-amide, palm-amide-amide, amide-amide, palm-amide-amide, amide-amide-amide, palm-amide-amide-amide, amide-amide, palm-amide-amide, palm-amide-amide, amide-amide, amide-amide, amide-amide, Palm-amide's - amide-Monoisopropanolamine, Palmamida-Monoethanolamine, PaImamide-Diethanolamine, Palmamida-Monoisopropanolamine, Peanutamide-Monoethanolamine, Peanutamide-Diethanolamine, peanut-amide-Monoisopropanolamine, soy-amide- Diethanolamine, Tallamide-Diethanolamine, Tallamide-Diethanolamine, Tallamide-Diethanolamine, Tallamide-Diethanolamine, Tallamide-Diethanolamine - Diethanolamine (= Cocamide-DEA), Cocamide- Monoisopropanolamine (= Cocamide-MIPA), Stearamide- Monoisopropanolamine, Isoestearamide- Monoisopropanolamine, Lauramide-Monoisopropanolamine, Linoleamide- Monoisopropanolamine, Miristamide-Monoamine-propylene-monoamine-propylamine-monoamide-propanol na, with Cocamide-Monoethanolamine being very particularly preferred.
    [064] Particularly preferred compositions according to the invention comprise: BB) 33 parts by weight to 47 parts by weight of Sodium Diethyl-Hexyl-Sulfosuccinate; CC) 23 parts by weight to 28 parts by weight of Cocamidopropyl-Betaine; DD) 23 parts by weight to 28 parts by weight of at least one substance selected from Sodium Lauryl ether-Sulfate and Disodium Lauryl ether-Sulfosuccinate; and EE) 7 parts by weight to 10 parts by weight of Cocamide-DEA.
    [065] In one aspect of the invention, the compositions according to the invention comprise, in addition to components A) to D), a solvent such as, for example, water and / or propylene glycol, dipropylene glycol, ethanol, isopropanol, glycerol, in in particular water, preferably in an amount of 20 wt% to 85 wt%, preferably 30 wt% to 70 wt%, in particular preferably 40 wt% to 50 wt%, based on the total composition.
    [066] This gives the technical effect that the compositions can be fully formulated more easily, have better processability and are more stable during storage. In this aspect of the invention, it is preferred according to the invention if the sum of components A) to D) in the composition according to the invention is contained in an amount of 5% by weight to 80% by weight, preferably 8% by weight. weight to 70% by weight in particular preferably from 10% by weight to 60% by weight based on the total composition.
    [067] The compositions according to the invention are exceptionally suitable for incorporating large quantities of oil while maintaining structured formulations, in particular structured cosmetic formulations.
    [068] Consequently, the present invention further provides a structured formulation, in particular a cosmetic formulation, comprising: a composition according to the invention; and FF) at least one cosmetic oil in an amount of 11% by weight to 74% by weight, preferably 16% by weight to 60% by weight, in particular preferably 21% by weight to 55% by weight, where the percentages by weight refer to the total formulation.
    [069] Within the scope of the present invention, the terminology "structured formulation" should be understood with the meaning of a formulation that has viscosity, which merges with an increase in the shear rate, in the shear rate of the order of 0.1 to 100 s- 1 and that has a yield point of b 1 mPa. Both the viscosity and the yield point are determined using a rheometer, whose determination axis is stored in an air bearing.
    [070] The viscosity declines in the order of the shear rate set at 1-10 orders of magnitude, with 2-6 orders of magnitude being preferred. The determinations are made using a geometry between plates with a diameter of 40 mm at 25 ° C.
    [071] The yield point is determined in oscillation at a frequency of 1 Hz at 25 ° C with a geometry between plates with a diameter of 40 mm. The shear force is varied here from 0.001-100 Pa and the criterion adopted for the yield point is the shear force in which a 51 deviation of the storage module from the plateau value of the viscoelastic range of linearity is achieved.
    [072] Preferred structured formulations according to the invention have a yield point greater than 0.001 Pa and in particular preferably 1-100 Pa. It is particularly preferred in that relationship that the yield point greater than 0.001 Pa and preferably 1-100 Pa Pa is present in the absence of polymeric rheological additives in the formulation according to the invention.
    [073] Cosmetic oils that can be used are substances such as silicone oils, functionalized silicones, mineral oils, fatty acid esters, natural oils such as vegetable oils, animal oils and mixtures thereof.
    [074] Preferred formulations according to the invention comprise Cyclopentassiloxane, Cyclomethicone, Dimethicone, Dimethicone, Amodimethicone, PEG / PPG Dimethicone, Cetyl-Dimethicone, Stearyl-Dimethicone, Stearoxy-Dimethicone, Behenoxy-Dimethicone, Poly-isobutene, Petrolate, Petrol Mineral, Hydrogenated Polydodecene, Hydrogenated Polydecene, Polydecene, Isoamyl-Cocoate, PPG-3-Miristyl-Ether, PPG-11- Stearyl-Ether, Dicaprilil-Ether, Dicaprilyl-Carbonate, Cetearyl-Isononanoate, Cetyl-Ethyl-Hexanoate, Diethyl Hexyl-Carbonate, Cetyl-Ricinoleate, Miristil-Myristate, Stearyl-Heptanoate, Decyl-Cocoate, Decyl-Oleate, PPG-15-Stearyl-Ether, Octyldodecanol, Isocetyl-Palmitate, Cetearyl-Ethyl-Hexanoate, Ethyl-Hexyl-Stearate, Isopropyl-Palmitate, PPG-14-Butyl-Ether, Tri-isostearin, Alkyl-Benzoate C12-15, Phenoxyethyl-Caprylate, Isopropyl-myristate, Caprilic / Capric Triglyceride, sunflower oil, olive oil, argan oil, mineral oil , castor oil, coconut oil, palm oil, peanut oil , avocado oil, almond oil, jojoba oil, corn oil, rapeseed oil, sesame oil, soybean oil, wheat germ oil, walnut oil, oleyl erucate and mixtures thereof. Preferred formulations according to the invention comprise components A) to E) in a weight ratio between the sum of components A) to D) and component E) from 1: 1.1 to 1:10, preferably from 1: 1.5 to 1 : 5, in particular preferably from 1: 2 to 1: 4.
    [075] Preferred structured formulations suitably according to the invention comprise compositions according to the invention specified above as preferred according to the invention.
    [076] Preferred formulations according to the invention comprise components A) to D) in total in an amount of 5% by weight to 35% by weight, preferably 8% by weight to 25% by weight, in particular preferably 11% by weight to 20% by weight, where the weight percentages refer to the total formulation.
    [077] Preferred formulations according to the invention comprise components A) to C) in total in an amount of 7% by weight to 16% by weight, the percentages by weight refer to the total formulation.
    [078] The formulations according to the invention are preferably aqueous formulations which preferably comprise water in an amount of 5% by weight to 80% by weight, preferably 20% by weight to 75% by weight, in particular preferably 30% by weight. weight to 60% by weight, where the weight percentages refer to the total formulation.
    [079] The formulations according to the invention are in particular cosmetic care and cleansing formulations, in particular for the skin and supplements for the skin.
    [080] The term "care formulation" is understood in this document as a formulation that satisfies the purpose of restoring an object to its original form, reducing or preventing the effects of external influences (eg, time, light, temperature, pressure, particles suspended in the air, chemical reaction with other compounds that come into contact with the object), such as aging, particles suspended in the air, material fatigue, discoloration, or even improving the object's desired positive properties.
    [081] Thus, the formulations according to the invention include liquid soaps, shower gels, oil baths, makeup removers or shampoos, bubble baths, hair shampoos, 2 in 1 shampoos, hair rinse products, solutions for permanent and neutralizing, hair color shampoos, hair fixing compositions, hair treatments, hair styling preparations, expansion-drying lotions, foam fixing compositions, conditioners that are not intended to be removed, hair straightening compositions, gloss enhancement compositions , and compositions for hair coloring.
    [082] Cosmetic care and cleaning formulations according to the invention may, for example, comprise at least one additional component selected from the group of non-ionic surfactants: emollients, emulsifiers, thickeners / viscosity regulators / stabilizers, antioxidants, hydrotropes (or polyols), solids and fillers, pearly shine additives, deodorant and antiperspirant active ingredients, insect repellents, self-tanning agents, preservatives, conditioners, perfumes, dyes, active cosmetic ingredients, care additives, super-fatty agents, solvents.
    [083] Substances that can be used as reference representatives of the individual groups are known to persons specialized in the subject and can be found for example purposes in EP 2273966A1. This patent application is incorporated in the terms described in this report as a reference and, therefore, is part of the description.
    [084] With regard to other optional components and the quantities of those components used, express reference is made to the relevant manuals known to experts in the field, such as K. Schrader, "Grundlagen und Rezepturen der Kosmetika" [Fundamentals and Formulations of Cosmetics], 2nd edition, pages 329 to 341, Hüthig Buch Verlag Heidelberg.
    [085] The quantities of the particular additives are determined by the intended use.
    [086] Typical guide formulations for the respective applications are known in the prior art and are contained for example in the manufacturers' brochures on the particular basic materials and active ingredients. These existing formulations can usually be adopted unchanged. If necessary, the desired modifications can, however, be carried out without complication through simple experiments for the purposes of adaptation and improvement.
    [087] The present invention further provides a process for preparing structured formulations, comprising the steps of: 1) providing a composition according to the invention; 2) mixing the composition according to the invention with E) at least one cosmetic oil to generate a structured formulation comprising the oil in an amount of 11% by weight to 74% by weight, preferably 16% by weight to 60% by weight , in particular preferably 21% by weight to 55% by weight, wherein the weight percentages for cosmetic oil refer to the total formulation.
    [088] According to the invention, it is preferable that the process according to the invention is correspondingly carried out with compositions according to the invention specified above as preferred according to the invention and with components E) specified above as preferred.
    [089] Preferred processes according to the invention are carried out with compositions according to the invention which additionally comprise a solvent such as, for example, water and / or propylene glycol, dipropylene glycol, ethanol, isopropanol, glycerol, in particular water, preferably in an amount of 20 wt% to 85 wt%, preferably 30 wt% to 70 wt%, in particular preferably 40 wt% to 50 wt%, based on the total composition used in step 1) process.
    [090] According to the invention, the process according to the invention is preferably carried out so that amounts of components A) to D) from 5% by weight to 35% by weight, preferably 8% by weight to 25% by weight. weight, in particular preferably 11% by weight to 20% by weight, are present in the resulting formulation, where the weight percentages refer to the total formulation.
    [091] According to the invention, the process according to the invention is preferably carried out with quantities of components A) to E) in a weight ratio between the sum of components A) to D) and component E) of 1: 1.1 to 1:10, preferably from 1: 1.5 to 1: 5, in particular preferably from 1: 2 to 1: 4.
    [092] Step 2) of the process according to the invention preferably comprises an emulsification of the components present.
    [093] In a preferred process according to the invention, water is present in an amount of 5% by weight to 80% by weight, preferably 20% by weight to 75% by weight, in particular preferably 30% by weight at 60 % by weight, where the percentages by weight refer to the total formulation obtained by the process according to the invention.
    [094] An alternative process according to the invention for preparing the formulations structured according to the invention, which constitutes a further topic of the present invention, comprises the steps of: a) providing a composition comprising: B) 15 parts by weight to 40 parts by weight, preferably 22 parts by weight to 32 parts by weight, in particular preferably 23 parts by weight to 28 parts by weight, of at least one amphoteric surfactant; C) 15 parts by weight to 40 parts by weight / preferably 22 parts by weight to 32 parts by weight / by weight preferably 23 parts by weight to 28 tonnes to parts by weight of at least one anionic surfactant; D) 0 parts by weight to 15 parts by weight> 4 = weight, preferably 5 parts by weight to 12 parts by weight, in particular preferably 7 parts by weight to 1 parts by weight, of at least one hydrophobic thickener; b) adding and mixing the components. leiiuet. A) and E) the composition of step a) of the process: A) 20 parts by weight to 67 parts by weight, preferably 25 parts by weight to 57 parts by weight, in particular preferably 33 parts by weight to 47 parts by weight, at least one substance selected from dialkyl-sulfosuccinates and dialkyl-methylsulfosuccinates; and E) at least one cosmetic oil in an amount of 11% by weight to 74% by weight, preferably 16% by weight to 60% by weight, in particular preferably 21% θm by weight to 55% by weight, where the percentages by weight for cosmetic oil refer to the total formulation to be obtained and in which the sum of parts by weight of components A) to D) makes 100 parts by weight.
    [095] Components A) and E) can be added according to the invention in step b) of the process in any desired order. It is possible to add E) and then A) or first A) and then E). Components A) and E) can also be at least partially mixed and then added at least partially in accordance with the invention in the form of a mixture in step b) of the process.
    [096] Components A) to E) used in the alternative process according to the invention correspond to the components present in formulations structured according to the invention. According to the invention, it is preferable that the process according to the invention is correspondingly conducted with components A) to D) of the compositions according to the invention specified above as preferred according to the invention and also with component E) of the structured formulations according to the invention specified above as preferred.
    [097] According to the invention, the alternative process according to the invention is preferably conducted in such a way that quantities of components A) to D) from 5% by weight to 35% by weight, preferably 8% by weight at 25 % by weight, in particular preferably 11% by weight to 20% by weight are present in the resulting formulation, where the percentages by weight refer to the total formulation.
    [098] According to the invention, the alternative process according to the invention is preferably carried out with quantities of components A) to E) in a weight ratio between the sum of components A) to D) and component E) of 1 : 1.1 to 1:10, preferably from 1: 1.5 to 1: 5, in particular preferably from 1: 2 to 1: 4.
    [099] Step b) of the alternative process according to the invention preferably comprises an emulsification of the components present.
    [0100] In a preferred alternative process according to the invention, water is present in an amount of 5% by weight to 80% by weight, preferably 20% by weight to 75% by weight, in particular preferably 30% by weight at 60% by weight, where the weight percentages refer to the total formulation obtained by the process according to the invention.
    [0101] The examples listed below describe the present invention by way of example, with no intention of restricting the invention, the scope of which is understandable based on the entire description and the claims, in relation to the modalities specified in the examples.
    [0102] The following figures are part of the examples.
    [0103] Figure 1: Results of the foam test on the measuring cylinder. Left (BW004): formulation comprising a surfactant system according to the previous technology; center (235) and right (236): formulations according to the invention. Examples: Examples 1 to 34, formulations with a high oil content


    Example 35: Technical foam measurements SITA R-2000 Foam Tester:
    [0104] In order to evaluate the foam properties and in particular the foaming capacity, tests were conducted with the foam analyst Sita (SITA R-2000 Foam Tester, SITA Messtechnik GmbH, Germany). To that end, formulations according to the invention were tested against a product on the market, that is, the comparative example "DG Deeply Moisturizing Body Wash" (PA) according to the prior art. The "DG Deeply Moisturizing Body Wash" includes a composition structured according to WO 20081 18381.
    [0105] The process was carried out at T = 30 ° C, using water with a hardness of 10 ° dH (hardness of German grade), at a pH ~ 6 and with a rotational speed of 1,500 rpm.
    [0106] The table contains the foam heights (in mL) after different times (10-100 s) of formulations according to the invention, which all comprise 3% Sodium Lauryl Ether Sulfate, Cocamido-propyl Betaine at 31, Cocamide -MEA at 1% and sunflower oil at 50% as well as a variable proportion of Diethylhexyl-Sulfosuccinate Sodium.

    [0107] The results first show that the foam heights of the compositions according to the invention are significantly higher than those according to the prior art.
    [0108] In addition, it was possible to show that, as a result of a large amount of Sodium Diethyl-Hexyl-Sulfosuccinate in the formulations according to the invention, the volume of foam can be increased; Diethyl-Hexyl-Sulfosuccinate Sodium can therefore be considered a quickly foaming surfactant in the formulation.

    [0109] As the exact proportion of oil in the prior art formulation was not known, formulations with different amounts of oil (Oleyl-Erucate, TEGOSOFT OER) were also compared in the Sita foam test. The formulations again consisted of 3% Sodium Lauryl ether-Sulfate, 3% Cocamido-propyl Betaine, 1% Cocamide-MEA and Sodium Diethyl-Hexyl-Sulfosuccinate a

    [0110] It has been found that the formulations according to the invention exhibit higher volumes of foam than the formulation according to the prior art after a shorter period regardless of the proportion of oil.
    Foam test on measuring cylinders
    [0111] Three threaded and connected 250 mL measuring cylinders were filled with 10 grams of formulation and 20 g of water. By stirring with a glass stick, the entire mixture of the formulations with the water was preserved. After closing the measuring cylinders, the preparation was stirred manually until a volume of 250 mL (foam and liquid) was reached in one of the measuring cylinders. The temperature during this experiment was 23 ° C. The instrument was then placed on a horizontal surface; after 30 seconds, a photograph was taken to document the foam volumes. The formulations consisted of formulations that were prepared with a surfactant mixture according to the prior art or in formulations according to the invention. The table below and Figure 1 summarize the results of the foam test on the cylinder.

    [0112] The results of the foam test on the measuring cylinder in Figure 1 show that the formulations according to the invention are better foaming agents than formulations according to the prior art. Furthermore, it has been surprisingly shown that formulations according to the invention containing a higher proportion of Diethylhexyl-Sulfosuccinate Sodium can be considered as surfactant mixtures with rapid foaming. Example 36: Improved foam sensory properties of the formulations according to the invention compared to the prior art
    [0113] In order to evaluate the foam properties and the skin treatment performance of the formulations according to the invention, a sensory analysis of hand washing was conducted in comparison with a product on the market, ie the comparative example "DG Deeply Moisturizing Body Wash "(PA) according to the prior technology. The "DG Deeply Moisturizing Body Wash" includes a composition structured according to WO 20081 18381.
    [0114] A group consisting of 10 trained test personnel washed their hands in a definite way and assessed foam properties and skin sensation using a scale from 1 (bad) to 5 (very good).
    [0115] The compositions of the formulations according to the invention are listed in Table 01. Tab. 01. Test formulations for hand washing analysis:

    [0116] The results of the sensory analysis are summarized in Table 02. Tab. 02. Results of the hand washing analysis:

    [0117] It is evident, based on the results of the analysis in Table 02, that the formulations according to the invention are superior in many application properties in comparison to the comparison formulation PA according to the prior art. In this context, the results of the formulations according to the invention can be designated as very good and exhibit a considerable improvement compared to the prior art.
    [0118] It is evident, based on the measurement values, that the formulations according to the invention result particularly in a significant improvement, specifically in terms of foaming behavior, volume of foam, creaminess of the foam and ease of rinsing. Other formulation examples








    权利要求:
    Claims (14)
    [0001]
    1. Composition CHARACTERIZED by the fact that it comprises: A) 20 parts by weight to 67 parts by weight, preferably 25 parts by weight to 57 parts by weight, in particular preferably 33 parts by weight to 47 parts by weight, of at least one substance selected from dialkyl-sulfosuccinates and dialkyl-methylsulfosuccinates, B) 15 parts by weight to 40 parts by weight, preferably 20 parts by weight to 32 parts by weight, in particular preferably 23 parts by weight to 28 parts by weight, at least an amphoteric surfactant, and C) 15 parts by weight to 40 parts by weight, preferably 20 parts by weight to 32 parts by weight, in particular preferably 23 parts by weight to 28 parts by weight, of at least one anionic surfactant.
    [0002]
    2. Composition according to claim 1, CHARACTERIZED by the fact that the dialkyl sulfosuccinate present and the dialkyl methyl sulfosuccinate are selected from the group consisting of dialkyl sulfosuccinates and / or dialkyl methyl sulfosuccinates in which the alkyl radicals each have , 4 to 24, preferably 6 to 18, in particular preferably 6 to 14 carbon atoms.
    [0003]
    3. Composition according to claim 1 or 2, CHARACTERIZED by the fact that the amphoteric surfactant present is selected from the group comprising, preferably, consisting of, alkyl betaine, alkylamidoalkyl-betaines, alkylamphacetates, alkylamphodiacetates , alkyl-amphopropionates, alkyl-amphodipropionates, alkyl-sultaines, alkyl-hydroxy-sultaines, alkylamine oxides, alkyl-amphoglycinates, alkyl-iminodiacetates, alkyl-iminodipropionates, alkyl-amphiopropylsulfonates and also alkali metal, alkali metal or alkaline earth metal arnonium salts of alkyl amphocarboxyglycinates and alkyl amphocarboxypropionates.
    [0004]
    4. Composition according to any one of the preceding claims, CHARACTERIZED by the fact that the anionic surfactant present is selected from the group comprising, preferably consists of, alkyl sulfates, alkyl ether sulfates, optionally alkoxylated sulfosuccinates, optionally alkoxylated methylsulfosuccinates , optionally alkoxylated sulphonates, optionally alkoxylated glycinates, optionally alkoxylated glutamates, optionally alkoxylated isethionates, optionally alkoxylated carboxylates, optionally alkoxylated anisates, optionally alkoxylated levulinates, optionally alkoxylated oxides, optionally alkoxylated oxides, optionally alkoxylated oxides, optionally alkoxylated oxides alkoxylated sulfoacetates, optionally alkoxylated sulfosuccinates, optionally alkoxylated sarcosinates and optionally alkoxylated phosphonates.
    [0005]
    Composition according to any one of the preceding claims, CHARACTERIZED by the fact that it comprises D) 0 parts by weight to 15 parts by weight, preferably 5 parts by weight to 12 parts by weight, in particular preferably 7 parts by weight to 10 parts by weight of at least one hydrophobic thickener.
    [0006]
    6. Composition, according to any one of the preceding claims, CHARACTERIZED by the fact that the hydrophobic thickener present is selected from the group that comprises, preferably consists of, reaction products of at least one fatty acid and / or at least one ester of fatty acid, such as fatty acid esters with glycerol, methyl fatty acid esters and ethyl fatty acid esters, with at least one primary or secondary amine, wherein the amine preferably also also comprises one or more other functional groups such as, for example, alcohols, and cationic surfactants in which, at pH 7 and 20 ° C, at least 90 mol% of the molecules have at least one positively charged group and preferably do not have an isoelectric point of pHIEP = 1-12 at 25 ° C, the determination being made in a 10 millimolar aqueous potassium chloride solution as standard electrolyte.
    [0007]
    7. Composition, according to any of the preceding claims, CHARACTERIZED by the fact that it comprises a solvent.
    [0008]
    8. Structured formulation, CHARACTERIZED by the fact that it comprises a composition as defined in any of the preceding claims and E) at least one cosmetic oil in an amount of 11% by weight to 74% by weight, preferably 16% by weight at 60 % by weight, in particular preferably 21% by weight to 55% by weight, where the percentages by weight refer to the total formulation.
    [0009]
    9. Structured formulation according to claim 8, CHARACTERIZED by the fact that it comprises components A) to D) in total in an amount of 5% by weight to 35% by weight, preferably 8% by weight to 25% in weight, in particular preferably 11% by weight to 20% by weight, where the weight percentages refer to the total formulation.
    [0010]
    10. Structured formulation, according to claim 8 or 9, CHARACTERIZED by having a yield point greater than 0.001 Pa.
    [0011]
    11. Structured formulation according to any one of claims 8 to 10, CHARACTERIZED by the fact that the cosmetic oil is selected from the group of silicone oils, functionalized silicones, mineral oils, fatty acid esters, natural oils such as vegetable oils , animal oils and mixtures thereof.
    [0012]
    12. Structured formulation according to any of claims 8 to 11, CHARACTERIZED by the fact that it is a formulation for cosmetic and cleansing care, in particular for skin and skin supplements.
    [0013]
    13. Process for preparing structured formulations, CHARACTERIZED in that it comprises the steps of 1) Providing a composition as defined in any one of claims 1 to 7, 2) mixing the composition according to the invention with, E) at least a cosmetic oil for producing a structured formulation comprising the oil in an amount of 11% by weight to 74% by weight, preferably 16% by weight to 60% by weight, in particular preferably 21% by weight to 55% by weight that the weight percentages refer to the total formulation.
    [0014]
    14. Process for preparing structured formulations, CHARACTERIZED by the fact that it comprises the steps of a) providing a composition comprising B) 15 parts by weight to 40 parts by weight, preferably 22 parts by weight to 32 parts by weight, in particular preferably 23 parts by weight to 28 parts by weight, of at least one amphoteric surfactant, C) 15 parts by weight to 40 parts by weight, preferably 22 parts by weight to 32 parts by weight, in particular preferably 23 parts by weight to 28 parts by weight of at least one anionic surfactant, and D) 0 parts by weight to 15 parts by weight, preferably 5 parts by weight to 12 parts by weight, in particular preferably 7 parts by weight to 10 parts by weight, at least minus a hydrophobic thickener, b) adding and mixing components A) and E) to the composition from step a) of the process, A) 20 parts by weight to 67 parts by weight, preferably 25 parts by weight to 57 parts by weight , in particular preferably 33 p gear by weight to 47 parts by weight, of at least one substance selected from dialkyl sulfosuccinates and dialkyl methyl sulfosuccinates, and E) at least one cosmetic oil in an amount of 11% by weight to 74% by weight, preferably 16% by weight weight to 60% by weight, in particular preferably 21% by weight to 55% by weight, where the weight percentages for cosmetic oil refer to the total formulation to be obtained, and where the sum of the parts by weight of the components A) to D) amounts to 100 parts by weight.
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    同族专利:
    公开号 | 公开日
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    EP2932959A1|2015-10-21|
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    US9320697B2|2016-04-26|
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    法律状态:
    2018-02-06| B12F| Appeal: other appeals|
    2019-10-29| B03A| Publication of an application: publication of a patent application or of a certificate of addition of invention|
    2019-11-05| B06U| Preliminary requirement: requests with searches performed by other patent offices: suspension of the patent application procedure|
    2019-11-05| B25A| Requested transfer of rights approved|Owner name: EVONIK DEGUSSA GMBH (DE) |
    2020-02-27| B25D| Requested change of name of applicant approved|Owner name: EVONIK OPERATIONS GMBH (DE) |
    2020-03-10| B25D| Requested change of name of applicant approved|Owner name: EVONIK OPERATIONS GMBH (DE) |
    2020-03-10| B150| Others concerning applications: publication cancelled|Free format text: ANULADA A PUBLICACAO CODIGO 15.21 NA RPI NO 2445 DE 14/11/2017 POR TER SIDO INDEVIDA.15.21 ANULADO PARA FINS DE PROSSEGUIMENTO DO FLUXO PROCESSUAL DO PEDIDO EM ATENDIMENTO AO PARECER RECURSAL QUE REFORMOU A DECISAO EM REFERENCIA |
    2020-08-18| B09A| Decision: intention to grant|
    2020-11-10| B16A| Patent or certificate of addition of invention granted|Free format text: PRAZO DE VALIDADE: 20 (VINTE) ANOS CONTADOS A PARTIR DE 17/04/2015, OBSERVADAS AS CONDICOES LEGAIS. |
    优先权:
    申请号 | 申请日 | 专利标题
    DE102014207386.3A|DE102014207386A1|2014-04-17|2014-04-17|Surfactant compositions and high oily formulations containing these|
    DE102014207386.3|2014-04-17|
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